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1

Organoboranes for synthesis : Reaction of organoboranes with representative organic azides. A general stereospecific synthesis of secondary amines and N-substituted aziridines

Herbert C. Brown, M.Mark Midland, Alan B. Levy, H.C. Brown, R.B. Wetherill, Akira Suzuki, Sunao Sono, Mitsuomi Itoh

Journal:

Année:

1987

Langue:

english

Fichier:

PDF, 861 KB

english, 1987

2

Hydroboration of enol acetates derived from aldehydes. Nucleophilic Reduction of α-acetoxyorganoboranes with hydroborating agent

Akira Suzuki, Kenichi Ohmori, Hidenori Takenaka, Mitsuomi Itoh

Journal:

Tetrahedron Letters

Année:

1968

Langue:

english

Fichier:

PDF, 187 KB

english, 1968

3

Magnetic anisotropy of the cyclobutane system with a puckered structure

Naoya Nakagawa, Senro Saito, Akira Suzuki, Mitsuomi Itoh

Journal:

Tetrahedron Letters

Année:

1967

Langue:

english

Fichier:

PDF, 216 KB

english, 1967

4

Reactions of cuprous methyltrialkylborates obtainable from trialkylboranes with acrylonitrile, ethyl acrylate and 1-acyl-2-vinylcyclopropane. Convenient syntheses of nitriles, carboxylic esters and γ,δ-unsaturated ketones

Norio Miyaura, Mitsuomi Itoh, Akira Suzuki

Journal:

Tetrahedron Letters

Année:

1976

Langue:

english

Fichier:

PDF, 212 KB

english, 1976

5

The reaction of copper(I) methyltrialkylborates with ethyl β-bromocrylates. Stereospecific syntheses of (E)- and (Z)-α,β-unsaturated acid esters from organoboranes

Norio Miyaura, Norio Sasaki, Mitsuomi Itoh, Akira Suzuki

Journal:

Tetrahedron Letters

Année:

1977

Langue:

english

Fichier:

PDF, 131 KB

english, 1977

6

The synthesis of methoxycyclopropanes via the treatment of ate-complexes obtained from B-alkyl-9-borabicyclo[3,3,1]nonanes and lithium methoxyallene with acetic acid

Norio Miyaura, Tomohiro Yoshinari, Mitsuomi Itoh, Akira Suzuki

Journal:

Tetrahedron Letters

Année:

1980

Langue:

english

Fichier:

PDF, 179 KB

english, 1980

7

Reaction of organoboranes with methoxycarbene, and reaction of dichloromethyl methyl ether with at-complex obtained from organoboranes and methyl lithium

Akira Suzuki, Seichi Nozawa, Norio Miyaura, Mitsuomi Itoh, Herbert C. Brown

Journal:

Tetrahedron Letters

Année:

1969

Langue:

english

Fichier:

PDF, 183 KB

english, 1969

8

Reaction of lithium alkynyltrialkylborates with propionic acid. General and convenient syntheses of internal and terminal olefins using organoboranes

Norio Miyaura, Tomohiro Yoshinari, Mitsuomi Itoh, Akira Suzuki

Journal:

Tetrahedron Letters

Année:

1974

Langue:

english

Fichier:

PDF, 245 KB

english, 1974

9

The coupling reaction of copper(I) methyltrialkylborates with aroyl chlorides. A convenient synthesis of alkyl aryl ketones from organoboranes

Norio Miyaura, Norio Sasaki, Mitsuomi Itoh, Akira Suzuki

Journal:

Tetrahedron Letters

Année:

1977

Langue:

english

Fichier:

PDF, 129 KB

english, 1977

10

On the synthetic approach to the protopine alkaloids

Kazuhiko Orito, Yoshitaka Kurokawa, Mitsuomi Itoh

Journal:

Année:

1980

Langue:

english

Fichier:

PDF, 511 KB

english, 1980

11

Benzolactams. II. Synthesis of tetrahydrobenz[d]indeno-[1,2-b]azepines and their 12-Oxo derivatives

Kazuhiko Orito, Harumi Kaga, Mitsuomi Itoh, S. Osmund De Silva, Richard H. Manske, Russel Rodrigo

Journal:

Journal of Heterocyclic Chemistry

Année:

1980

Fichier:

PDF, 620 KB

1980

12

Catalytic properties of BF3-treated aluminas: III. Influence of precalcination temperature on the product selectivity in 1-butene isomerization and n-BuOH dehydration

Kanjiro Matsuura, Akira Suzuki, Mitsuomi Itoh

Journal:

Journal of Catalysis

Année:

1971

Langue:

english

Fichier:

PDF, 229 KB

english, 1971

13

Catalytic properties of BF3-treated aluminas: V. Vapor-phase alkylation of toluene with ethylene using BF3-treated aluminas

Kanjiro Matsuura, Takaaki Watanabe, Akira Suzuki, Mitsuomi Itoh

Journal:

Journal of Catalysis

Année:

1972

Langue:

english

Fichier:

PDF, 607 KB

english, 1972

14

Development of highly stable galectins: Truncation of the linker peptide confers protease-resistance on tandem-repeat type galectins

Nozomu Nishi, Aiko Itoh, Aimi Fujiyama, Naoko Yoshida, Shin-ichi Araya, Mitsuomi Hirashima, Hiroki Shoji, Takanori Nakamura

Journal:

Année:

2005

Langue:

english

Fichier:

PDF, 305 KB

english, 2005

15

Reaction of representative organic azides with triethylborane. New route to secondary amines

Brown, Herbert C., Suzui, Akira, Sonao, Sunao, Itoh, Mitsuomi, Midland, M. Mark

Journal:

Journal of the American Chemical Society

Année:

1971

Langue:

english

Fichier:

PDF, 260 KB

english, 1971

16

Two novel reactions of monomeric formaldehyde with trialkylboranes. Remarkably rapid elimination diverted by oxygen to a free-radical chain addition

Miyaura, Norio, Itoh, Mitsuomi, Suzuki, Akira, Brown, Herbert Charles, Midland, M. Mark, Jacob, Peyton

Journal:

Journal of the American Chemical Society

Année:

1972

Langue:

english

Fichier:

PDF, 262 KB

english, 1972

17

Oxygen-induced reactions of organoboranes with acetylacetylene. Convenient new synthesis of .alpha.,.beta.-unsaturated ketones via hydroboration

Suzuki, Akira., Nozawa, Seichi., Itoh, Mitsuomi., Brown, Herbert Charles., Kabalka, George W., Holland, George W.

Journal:

Journal of the American Chemical Society

Année:

1970

Langue:

english

Fichier:

PDF, 371 KB

english, 1970

18

Facile reaction of organoboranes with methyl vinyl ketone. Convenient new ketone synthesis via hydroboration

Suzuki, Akira., Arase, Akira., Matsumoto, Hachiro., Itoh, Mitsuomi., Brown, Herbert Charles., Rogic, Milorad M., Rathke, Michael W.

Journal:

Journal of the American Chemical Society

Année:

1967

Langue:

english

Fichier:

PDF, 247 KB

english, 1967

19

Inhibition of the reaction of organoboranes with .alpha.,.beta.-unsaturated carbonyl derivatives by galvinoxyl. Evidence for a free-radical chain mechanism

Kabalka, George W., Brown, Herbert Charles., Suzuki, Akira., Honma, Shiro., Arase, Akira., Itoh, Mitsuomi.

Journal:

Journal of the American Chemical Society

Année:

1970

Langue:

english

Fichier:

PDF, 329 KB

english, 1970

20

Convenient and general synthesis of acetylenes via the reaction of iodine with lithium l-alkynyltriorganoborates

Suzuki, Akira., Miyaura, Norio., Abiko, Shigeo., Itoh, Mitsuomi., Brown, Herbert C., Sinclair, James A., Midland, M. Mark.

Journal:

Journal of the American Chemical Society

Année:

1973

Langue:

english

Fichier:

PDF, 264 KB

english, 1973

21

Oxygen-induced reaction of trialkylboranes with alkyl iodides. Facile coupling of benzylic and allylic iodides via triethylborane

Brown, Herbert Charles, Suzuki, Akira, Nozawa, Seichi, Harada, Masahiro, Itoh, Mitsuomi, Midland, M. Mark

Journal:

Journal of the American Chemical Society

Année:

1971

Langue:

english

Fichier:

PDF, 294 KB

english, 1971

22

Hydroboration of terpenes. V. Isomerization of (+)-sabinene to (+)-.alpha.-thujene. Hydroboration of (+)-sabinene and (+).alpha.-thujene with configurational assignments for the thujanols

Acharya, Shrinivas P., Brown, Herbert Charles, Suzuki, Akira, Nozawa, Seichi, Itoh, Mitsuomi

Journal:

Journal of Organic Chemistry

Année:

1969

Langue:

english

Fichier:

PDF, 1.09 MB

english, 1969

23

Vinylic organoboranes. 1. A convenient synthesis of acetylenes via the reaction of lithium (1-alkynyl) organoborates with iodine

Suzuki, Akira, Miyaura, Norio, Abiko, Shigeo, Itoh, Mitsuomi, Midland, M. Mark, Sinclair, James A., Brown, Herbert C.

Journal:

Journal of Organic Chemistry

Année:

1986

Langue:

english

Fichier:

PDF, 678 KB

english, 1986

24

Photochemical reaction of .alpha.,.beta.-epoxy esters in protic solvent

Tokuda, Masao, Chung, V. V., Suzuki, Akira, Itoh, Mitsuomi

Journal:

Journal of Organic Chemistry

Année:

1975

Langue:

english

Fichier:

PDF, 306 KB

english, 1975

25

Radiation-induced and electrochemical formation of 3-substituted 4,4-dimethyl-.gamma.-butyrolactone from .alpha.,.beta.-unsaturated ester

Itoh, Mitsuomi., Taguchi, Toru., Vo Van Chung, ., Tokuda, Masao., Suzuki, Akira.

Journal:

Journal of Organic Chemistry

Année:

1972

Langue:

english

Fichier:

PDF, 369 KB

english, 1972

26

New four-carbon-atom homologation involving the free-radical chain reaction of 1,3-butadiene monoxide with organoboranes. Synthesis of 4-alkyl-2-buten-1-ols from olefins via hydroboration

Brown, Herbert Charles, Suzuki, Akira, Miyaura, Norio, Itoh, Mitsuomi, Holland, George W., Negishi, Eichi

Journal:

Journal of the American Chemical Society

Année:

1971

Langue:

english

Fichier:

PDF, 271 KB

english, 1971

27

Photochemical reaction of trialkylboranes in alcohols. Convenient synthesis of 2-alkyl-1,3,2-dioxaborolanes

Tokuda, Masao, Van Chung, Vo, Inagaki, Kazuhiko, Itoh, Mitsuomi

Journal:

Journal of the Chemical Society Chemical Communications

Année:

1977

Langue:

english

Fichier:

PDF, 184 KB

english, 1977

28

New cathodic reaction of phenylacetylene with alkyl halides

Tokuda, Masao, Taguchi, Toru, Nishio, Osamu, Itoh, Mitsuomi

Journal:

Journal of the Chemical Society Chemical Communications

Année:

1976

Langue:

english

Fichier:

PDF, 158 KB

english, 1976

29

New route to the protopanes

Orito, Kazuhiko, Itoh, Mitsuomi

Journal:

Journal of the Chemical Society Chemical Communications

Année:

1978

Langue:

english

Fichier:

PDF, 152 KB

english, 1978

30

Reaction of the cyclic organoboranes from dienes with methyl vinyl ketone. A convenient synthesis of ?-hydroxy-ketones from dienes via hydroboration

Suzuki, Akira, Nozawa, Seichi, Itoh, Mitsuomi, Brown, Herbert C., Negishi, Ei-ichi, Gupta, Shyam K.

Journal:

Journal of the Chemical Society D Chemical Communications

Année:

1969

Langue:

english

Fichier:

PDF, 295 KB

english, 1969

31

Electrochemical reductive cyclisation of dimethyl 2,(??1)-dibromoalkanedioates

Satoh, Shohei, Itoh, Mitsuomi, Tokuda, Masao

Journal:

Journal of the Chemical Society Chemical Communications

Année:

1978

Langue:

english

Fichier:

PDF, 173 KB

english, 1978

32

The Reactions of Organoboranes and Lithium Dialkylcuprates with 1-Acyl-2-vinylcyclopropanes. A Convenient New Route to γ,δ-Unsaturated Ketone Synthesis

MIYAURA, Norio, ITOH, Mitsuomi, SASAKI, Norio, SUZUKI, Akira

Journal:

Année:

1975

Fichier:

PDF, 163 KB

1975

33

A Convenient and General Synthesis of 2-Alkynoates or 1-Alkynyl Aryl Ketones via the Reaction of Iodine with the Ate-complexes Obtained from Lithium Ethoxycarbonyl-or Aroylacetylenide and Trialkylboranes

YAMADA, Kinji, MIYAURA, Norio, ITOH, Mitsuomi, SUZUKI, Akira

Journal:

Année:

1977

Fichier:

PDF, 148 KB

1977

34

The Coupling Reaction of Copper(I) Methyltrialkylborates with Benzyl Bromides. A Convenient Synthesis of Alkylbenzenes from Organoboranes

MIYAURA, Norio, ITOH, Mitsuomi, SUZUKI, Akira

Journal:

Année:

1976

Fichier:

PDF, 130 KB

1976

35

The Oxygen-Induced Reactions of Organoboranes with 3,4-Epoxy-1-butynes. A New Route to Functionalized Allenes

SUZUKI, Akira, MIYAURA, Norio, ITOH, Mitsuomi, BROWN, Herbert C., JACOB, III, Peyton

Journal:

Année:

1973

Fichier:

PDF, 128 KB

1973

36

A New Electrochemical Synthesis of Nitroalkanes from Organoboranes

TAKAHASHI, Yuzuru, TOKUDA, Masao, ITOH, Mitsuomi, SUZUKI, Akira

Journal:

Année:

1976

Fichier:

PDF, 140 KB

1976

37

Photochemistry of Acetophenone and Acetaldehyde in Ether Solvent —Formation of Diastereoisomeric Alcohols

Tokuda, Masao, Hasegawa, Miki, Suzuki, Akira, Itoh, Mitsuomi

Journal:

Bulletin of the Chemical Society of Japan

Année:

1974

Fichier:

PDF, 346 KB

1974

38

Electrochemical Reaction of Organoboranes in the Presence of Propenoic Acid Esters. A Convenient Carboxylic Ester Synthesis from Organoboranes

Takahashi, Yuzuru, Yuasa, Kazuma, Tokuda, Masao, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Bulletin of the Chemical Society of Japan

Année:

1978

Fichier:

PDF, 375 KB

1978

39

The Reaction of Copper(I) Methyltrialkylborates with Allylic Halides or 2-Propynylic Halides

Miyaura, Norio, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Bulletin of the Chemical Society of Japan

Année:

1977

Fichier:

PDF, 274 KB

1977

40

A CONVENIENT STEREOSPECIFIC ALKYLATION OF PHENYLACETYLENE BY ELECTROCHEMICAL REACTION OF ORGANOBORANES

Takahashi, Yuzuru, Tokuda, Masao, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Chemistry Letters

Année:

1980

Langue:

english

Fichier:

PDF, 6.14 MB

english, 1980

41

A Study of the Structure of Pyridine Extracts from Coals by High Resolution Nuclear Magnetic Resonance Spectroscopy

Takeya, Gen, Itoh, Mitsuomi, Suzuki, Akira, Yokoyama, Susumu

Journal:

Bulletin of the Chemical Society of Japan

Année:

1963

Langue:

english

Fichier:

PDF, 3.83 MB

english, 1963

42

Catalytic Properties of BF 3 -treated Aluminas. IV. The Effect of BF 3 Adsorption on the Acidic Properties of Aluminum Oxides

Matsuura, Kanjiro, Suzuki, Akira, Itoh, Mitsuomi

Journal:

Bulletin of the Chemical Society of Japan

Année:

1972

Fichier:

PDF, 829 KB

1972

43

Photochemical Reaction of Ethyl 3-Methyl-3-phenylglycidate in Methanol and Ether Solvents

Chung, Vo Van, Tokuda, Masao, Suzuki, Akira, Itoh, Mitsuomi

Journal:

Bulletin of the Chemical Society of Japan

Année:

1976

Fichier:

PDF, 376 KB

1976

44

Addition Reaction of Copper(I) Methyltrialkylborates with Ethyl Propiolate. Stereospecific Synthesis of ( E )-α,β-Unsaturated Acid Esters

Yamada, Kinji, Miyaura, Norio, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Bulletin of the Chemical Society of Japan

Année:

1977

Fichier:

PDF, 270 KB

1977

45

Photochemical Reactions of 2-(Alkoxycarbonyl)-, 2-Cyano-, and 2-(Phenylthio)-cycloalkanones in Alcoholic Solution. Formation of ω-Substituted Esters

Tokuda, Masao, Watanabe, Yasuyuki, Itoh, Mitsuomi

Journal:

Bulletin of the Chemical Society of Japan

Année:

1978

Fichier:

PDF, 827 KB

1978

46

Electrochemical Vicinal Addition of Two Alkyl Groups to Phenyl Substituted Olefins and Diethyl Fumarate

Satoh, Sh\={o}hei, Taguchi, T\={o}ru, Itoh, Mitsuomi, Tokuda, Masao

Journal:

Bulletin of the Chemical Society of Japan

Année:

1979

Fichier:

PDF, 375 KB

1979

47

A CONVENIENT SYNTHESIS OF α-BROMOKETONES FROM VINYLOXYBORANES OBTAINED BY THE REACTION OF ORGANOBORANES WITH α, β-UNSATURATED KETONES

Miyaura, Norio, Harada, Masahiro, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Chemistry Letters

Année:

1973

Langue:

english

Fichier:

PDF, 6.69 MB

english, 1973

48

OXYGEN-INDUCED 1,4-ADDITION REACTION OF ORGANOBORANES TO CROTONALDIMINE

Miyaura, Norio, Kashiwagi, Masatoshi, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Chemistry Letters

Année:

1974

Langue:

english

Fichier:

PDF, 3.03 MB

english, 1974

49

REGIOSELECTIVE CLEAVAGE OF ARYL DECYL ETHERS WITH ALKALI METALS

Itoh, Mitsuomi, Yoshida, Shigeo, Ando, Toshiharu, Miyaura, Norio

Journal:

Chemistry Letters

Année:

1976

Langue:

english

Fichier:

PDF, 6.03 MB

english, 1976

50

FACILE ELECTROCHEMICAL ALKYLATION OF 1-ALKYNES WITH ORGANOBORANES

Takahashi, Yuzuru, Tokuda, Masao, Itoh, Mitsuomi, Suzuki, Akira

Journal:

Chemistry Letters

Année:

1977

Langue:

english

Fichier:

PDF, 5.06 MB

english, 1977